在蒸汽沉积的冰中脱和融化
Fabio Leoni1, Fausto Martelli1,2,3, John Russo1
1Dipartimento di Fisica, Università degli Studi di Roma La Sapienza, Piazzale Aldo Moro 5, Rome 00185, Italy.
The Journal of chemical physics
|September 8, 2025
概括
这项研究揭示了不同的无形冰在加热时如何融化和脱. 蒸汽沉积的冰,与灭的冰不同,在表面上融化,呈现独特的结构变化,表明稳定性提高.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 物理化学 物理化学
背景情况:
- 超稳定的玻璃,特别是无形玻璃,在热应力下表现出复杂的平衡动态.
- 了解脱玻和化对于材料科学和预测玻璃的行为至关重要.
- 最近的实验和理论兴趣集中在这些材料的加热协议上.
研究的目的:
- 研究常规灭 (QG) 和蒸气沉积 (DG) 无形冰的脱氧和融化动态.
- 为了将键网络统计与热过程中的结构稳定性相关联.
- 为了区分QG和DG无形冰之间的融化行为.
主要方法:
- 使用mW水模型进行模拟.
- 控制式加热坡道协议.
- 开发一种算法来重建键网络并分析键环统计数据.
- 在脱玻璃化和化过程中跟踪晶体和液体集群.
主要成果:
- 键环统计与玻璃结构稳定性和轨道相变化相关.
- QG在散装中融化,而DG则优先从自由表面融化.
- DG在表面附近显示出多余的5个成员环,促进了晶体核形成.
- DG显示了一个异常的Avrami指数,表明更高的动力稳定性.
结论:
- 在QG和DG无形冰中,融化行为和脱玻璃化途径显著不同.
- 键网络分析为无形固体的结构稳定性和相变提供了洞察力.
- DG的表面发起的化和异常动力学与其增强的动力稳定性有关.
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