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Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Formation of Complex Ions03:45

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
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Standard Electrode Potentials03:02

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On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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高性能硫化物固态电池电解质调节机制:一项审查

Keyu Chen1, Yuchuan Zhu1, Jiayang Li1

  • 1College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China.

Angewandte Chemie (International ed. in English)
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概括
此摘要是机器生成的。

硫化物固体电解质 (SE) 为全固态电池 (ASSB) 提供高导电性. 本综述详细介绍了提高SE稳定性和绩效的策略,并解决了未来发展的关键挑战.

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所有固态电池都是固态电池.化学稳定性 化学稳定性玻璃结构理论 玻璃结构理论软硬酸基理论硫化物固体电解质 硫化物固体电解质

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 硫化物固体电解质 (SE) 具有较高的离子导电性和机械强度.
  • 空气稳定性差和固体与固体接触阻碍了硫化物全固态电池 (ASSB) 的应用.

研究的目的:

  • 审查硫化物SEs.的历史发展和重大突破.
  • 讨论理论和策略,以改善硫化物SE的化学稳定性.
  • 探索热逃跑和反应机制,以提高稳定性和导电性.

主要方法:

  • 关于硫化物SE发展的文献综述.
  • 讨论硬-软-酸-和玻璃结构理论.
  • 分析SE机制的热力学和动力学方面.

主要成果:

  • 确定了改善硫化物SE化学稳定的关键策略.
  • 提供了有关热失控和反应机制的见解.
  • 强调当前的挑战和未来的研究方向.

结论:

  • 硫化物SE对ASSB来说是有希望的,但需要稳定性改进.
  • 对稳定性,导电性和接口工程的进一步研究至关重要.
  • 本综述为推进硫化SE技术提供了一个参考.