最佳的微合金增强了SASS/Q235接腐蚀和抗菌性能
Xingbin Liu1,2,3,4, Quantong Jiang1,2,3,4, Haojun Li1,2,3,4
1State Key Laboratory of Advanced Marine Materials, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China.
iScience
|September 10, 2025
概括
将 (Ce) 添加到超奥氏体不钢 (SASS) 中,可以提高接接头的耐腐蚀性和抗菌性. 最佳值为1.0重% Ce提炼了谷物结构并形成了保护膜,但过多的Ce加快了腐蚀.
科学领域:
- 材料科学 材料科学 材料科学
- 腐蚀工程 腐蚀工程
- 海洋技术 海洋技术
背景情况:
- 在海洋环境中,超奥氏体不钢 (SASS) 和碳钢 (Q235) 的接接头会受到蚀和抗菌性能差.
- 开发用于海洋基础设施的坚固材料需要解决这些具体挑战.
研究的目的:
- 为了研究 (Ce) 添加对Q235.5接SASS的微观结构,耐腐蚀性和抗菌性能的影响.
- 确定最佳的含量,以提高这些接接头在海洋环境中的性能.
主要方法:
- 对受热影响区域 (HAZ) 的微结构分析,以观察谷物精炼和阶段沉.
- 电化学测试,包括电荷转移电阻和被动电流密度测量.
- 抗菌试验评估对硫酸盐减少细菌 (SRB) 生存的影响.
主要成果:
- 1.0%重量Ce添加精炼HAZ颗粒大小从7μm到2μm,并抑制有害的西格玛相沉.
- 优化的含量显著提高了耐腐蚀性,将电荷转移电阻提高到2.2 × 103 Ω cm2,并将被动电流密度降低到0.12 μA/cm2.
- 1.0重%的Ce表现出强烈的抗菌活性,通过破坏细菌膜,将SRB生存率降至<1%,而较高度 (>1.5重%) 则被证明是有害的.
结论:
- 是一种有前途的添加剂,可以提高SASS/Q235接接头在海洋应用中的性能.
- 特定的度 (1.0重量%) 提供了增强的耐腐蚀性和抗菌性能的双重好处.
- 仔细控制含量至关重要,因为过量可能会对材料性能产生负面影响.
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