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Updated: Jan 18, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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双铜催化酶选择性脱碳化 [2 + 3] 循环添加乙烯基循环碳酸盐/碳酸盐与4-基氨酸

Wen-Ya Lu1,2, Yong You1, Zhen-Hua Wang1

  • 1Innovation Research Center of Chiral Drugs, Institute for Advanced Study, Chengdu University, Chengdu 610106, China.

Organic letters
|September 12, 2025
PubMed
概括

一种新的双铜催化反应使光学纯净的二水[3,2-c]胺衍生物的合成成为可能. 这种高效的方法使用乙烯基循环碳酸盐/碳酸盐作为独特的构建模块,用于酶选择性循环添加.

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Cycloaddition Reactions: Overview01:16

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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