热解温度和修改方法对水皮衍生的生物炭特性和重金属吸附的影响
Zhaoqin Huang1, Qin Wang2, Yufeng Zhang2
1College of Environmental Ecology, Jiangsu Open University, Nanjing 210017, China.
Molecules (Basel, Switzerland)
|September 13, 2025
概括
用氧化物 (KOH) 修改的米生物炭有效地从水中去除重金属 (Cd) 和 (Pb). KOH的修改显著增强了生物炭.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学 化学 化学
背景情况:
- 水中的重金属污染对环境和健康构成重大风险.
- 从农业废物中提取的生物炭提供了一个可持续的吸附材料.
- 优化生物炭特性对于有效去除重金属至关重要.
研究的目的:
- 为了研究热解温度和化学修饰对大米皮生物炭特性的影响.
- 为了评估修改生物炭对 (Cd(II)) 和 (Pb(II)) 除去的吸附能力.
- 为了确定增强重金属吸附的最佳修改策略.
主要方法:
- 米生物炭是在300,400和500°C的热解温度下制备的.
- 生物炭使用酸 (HNO3) 和氧化 (KOH) 进行了修改.
- 物理化学性质和重金属吸附能力 (Cd (II),Pb (II)) 的特征.
主要成果:
- 热解温度的提高提高了生物炭的特定表面积和孔积.
- HNO3和KOH的修改显著改变了表面功能组,并改善了吸附.
- 用KOH修饰的生物炭 (KOH-BC300) 显示了最高的吸附能力:Cd (II) 的72.14 mg·g-1和Pb (II) 的170.84 mg·g-1 .
结论:
- KOH修饰比HNO3修饰更有效地增强重金属吸附在米生物炭上的重金属吸附.
- 含有氧的功能组在提高吸附性能方面,比特定表面积发挥更为关键的作用.
- 经KOH改性大米生物炭是一种有前途的吸附剂,用于废水处理和重金属整治.
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