波西多尼亚废弃灰的可持续价值化用于酸盐去除:在可变水化学下进行表面复合的方法
Jesús Mengual1, Juan A González2
1Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022 València, Spain.
Molecules (Basel, Switzerland)
|September 13, 2025
概括
热处理的波西多尼亚灰有效地从水中去除酸盐,为水污染提供可持续的解决方案. 这种生物基吸附剂还为沿海生物质利用提供了一个循环战略.
科学领域:
- 环境化学环境化学
- 水生生物缩管理水生生物缩管理
- 生物质的价值化 生物质的价值化
背景情况:
- 污染对地中海水生生态系统构成重大威胁,导致生物多样性减弱和生物多样性丧失.
- 波西多尼亚海洋 (海草) 的残留物构成了沿海生物量管理的挑战.
研究的目的:
- 调查热处理的波西多尼亚灰作为可持续吸附剂的酸盐去除效果.
- 使用新型表面复合模型 (SCM) 阐明酸盐吸附机制.
主要方法:
- 在各种水化学条件下 (酸盐度,pH,硬度,度) 进行了批量吸附实验.
- 光谱技术验证了一种新开发的表面复杂化模型 (SCM).
主要成果:
- 波西多尼亚灰具有很高的酸盐去除能力 (33.5-58.7 mg/g).
- 该SCM提供了机械洞察力,超过了传统的异热模型.
- 酸盐吸附取决于pH值,涉及表面复合和离子释放 (Ca2+,Mg2+),导致三元复合体的形成和沉.
- 在性条件下,与碳酸盐离子的竞争性吸附发生.
结论:
- 热处理的波西多尼亚灰是一种具有成本效益的,生物基吸附剂,用于酸盐去除.
- 这种方法提供了双重好处:减轻营养污染和提升沿海生物质的价值.
- 该研究提出了一个循环经济战略,用于管理和海草残留物利用.
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