基于PEF和PBF的环保混合物与氧化天然:解开结构与财产关系
Sandra Paszkiewicz1, Konrad Walkowiak1, Izabela Irska1
1Department of Materials Technologies, Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology, Piastow Av. 19, 70-310 Szczecin, Poland.
Materials (Basel, Switzerland)
|September 13, 2025
概括
准备了生物基聚乙烯2,5酸 (PEF) 和聚乙烯2,5酸 (PBF) 与环氧化天然 (epNR) 的环保聚合物混合物. 该研究描述了它们的可混合性,热性能和机械性能,揭示了epNR增强了灵活性,但降低了强度.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 可持续材料 可持续材料
背景情况:
- 开发生物基聚合物,如聚乙烯2,5酸 (PEF) 和聚乙烯2,5酸 (PBF),对于可持续替代石油塑料至关重要.
- 加入诸如环氧化天然 (epNR) 等添加剂可以改变聚合物的特性,但了解混合物行为至关重要.
研究的目的:
- 准备和描述PEF/epNR和PBF/epNR的环保聚合物混合物.
- 研究这些生物基聚合物混合物的可混合性,化学相互作用,热性能和机械行为.
- 评估epNR对PEF和PBF可处理性和性能的影响.
主要方法:
- 聚合物混合物通过两阶段化聚凝制备.
- 使用霍伊的方法进行混合性评估.
- 使用富里埃变换红外光谱法 (FTIR) 进行化学相互作用分析.
- 使用差分扫描热量测量 (DSC) 和热重力测量分析 (TGA) 评估热性质.
- 机械性能测试,包括拉力和硬度测试.
主要成果:
- 分析了PEF/PBF和epNR之间的可混合性和化学相互作用.
- 添加EPNR显著影响了化流量指数 (MFI),有限粘度数 (LVN) 和交叉链密度.
- 使用氧化起始温度 (OOT) 试验评估了热氧化稳定性.
- PEF/epNR混合物显示灵活性增加,但硬度和拉伸强度降低,epNR含量更高.
- PBF/epNR混合物显示拉伸强度和弹性模量降低,两种混合物类型的硬度降低.
结论:
- 氧化天然可以与生物基聚合物PEF和PBF混合.
- 添加epNR改变了PEF和PBF的可加工性,热稳定性和机械性能.
- 虽然epNR增强了灵活性,但它通常会降低这些生物基聚合物混合物的强度和刚度,根据特定的聚和epNR含量产生不同的效果.
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