在Zn-Mg合金中提高耐腐蚀性的PEO处理:电化学和结构分析
Ramona Cimpoeșu1, Sorin Georgian Moga2, Bogdan Istrate3
1Department of Materials Science, Faculty of Materials Science and Engineering, "Gheorghe Asachi" Technical University of Iasi, 41 Dimitrie Mangeron Blvd., 700050 Iasi, Romania.
Materials (Basel, Switzerland)
|September 13, 2025
概括
血电解氧化 (PEO) 处理显著提高了- (ZnMg) 合金的耐腐蚀性. 这种表面增强使得ZnMg合金更适合生物医学植入物和海洋环境等苛刻的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 表面工程是什么?表面工程是什么?
背景情况:
- 基于的合金对可生物降解的应用有前途,但耐腐蚀性较差.
- 有效的表面处理对于减轻- (ZnMg) 合金中的腐蚀至关重要.
- 血电解氧化 (PEO) 是一种具有合金保护潜力的表面改造技术.
研究的目的:
- 调查等离子电解氧化 (PEO) 对ZnMg合金腐蚀行为的影响.
- 描述PEO处理形成的保护性氧化物层.
- 评估PEO处理的ZnMg合金对腐蚀性环境的适用性.
主要方法:
- 通过造制备ZnMg合金.
- 使用等离子电解氧化 (PEO) 的表面处理.
- 使用Tafel偏振,循环偏振和电化学阻抗光谱 (EIS) 在0.9%NaCl中对腐蚀进行评估.
- 通过扫描电子显微镜 (SEM),EDX和X射线衍射 (XRD) 进行表面和结构分析.
主要成果:
- 经过PEO处理,腐蚀电流密度显著降低,极化电阻增加.
- 经过EIS分析,发现形成了一层具有独特电容性质的保护层.
- XRD证实了合金表面上与化环境相关的腐蚀产品的存在.
结论:
- PEO处理有效地提高了ZnMg合金的耐腐蚀性.
- 增强的腐蚀性能表明,经PEO处理的ZnMg合金可用于生物医学应用.
- 提高耐久性使这些合金适用于腐蚀率高的环境,例如海洋环境.
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