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冷却速率和固体分量的对Rheo-Die造中的α-Al相位演变的影响:相位场模拟和实验调查
Song Chen1,2,3, Wangwang Kuang4, Jian Feng1,2
1State Key Laboratory of Nonferrous Structural Materials, China GRINM Group Co., Ltd., Beijing 100088, China.
Materials (Basel, Switzerland)
|September 13, 2025
概括
这项研究揭示了在半固体造过程中冷却速度如何影响合金微结构. 高冷却速率促进了二次的形成,而较高的固体分数则限制了它.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 造技术 造技术 造技术
背景情况:
- 了解半固体金属造微结构对于材料性能至关重要.
- 高固体分量过程在控制微观结构方面存在独特的挑战.
- 现有的模型往往缺乏用于复杂冷却过渡的动态模拟能力.
研究的目的:
- 为了研究高固体分数半固体rheo-die造过程中的动态微观结构演变.
- 开发和验证一个相场模型,以模拟在不同冷却速率下持续固化.
- 在不同的加工条件下分析Al-7Si合金中α-Al相的形态演变.
主要方法:
- 开发了一种新的相场模型,将连续冷却与显式核结合在一起.
- 集成了旋转热平衡装置 (SEED) 用于泥制备.
- 进行了分级冷却模具实验,以确定可变的冷却速率和固体分数条件.
- 在Al-7Si合金上进行实验和模拟调查.
主要成果:
- 在I阶段泥制备过程中观察到初级α1-Al阶段的奥斯瓦尔德成熟 (0.1-0.3 K/s).
- 初级α1-Al在中度冷却速率 (15K/s) 下在第二阶段流模造中继续增长.
- 二次α2-Al形成高度依赖于冷却速度和固体分数.
- 高冷却速率 (150 K/s) 导致α2-Al的爆炸性核化,而中等速率 (15 K/s) 抑制了它.
- 高冷却速率提高了溶液的捕获和构成性的低冷却,促进了二级阶段的形成.
结论:
- 开发的相场模型准确地捕捉了在两阶段冷却过程中的微观结构演变.
- 冷却速度和固体分数是控制二次α2-Al形成的关键参数.
- 高冷却速率有利于通过溶液捕获形成二次相,而高固体分数通过减少凝固窗口来限制它.
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