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Updated: Jan 17, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
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通过化学相互作用控制聚合物电解质界面形态

Joseph A Dura1, Sangcheol Kim2, Kirt A Page3,4,5

  • 1NIST Center for Neutron Research, 100 Bureau Dr. Gaithersburg, Maryland 20899, United States.

Chemistry of materials : a publication of the American Chemical Society
|September 15, 2025
PubMed
概括

自组装的单层控制纳菲安.

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Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
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