对于平原主导硬碳阳极的硫介导脱和结合
Juan Chen1,2, Yuhao Lu3, Yi Zhang1,2
1Faculty of Materials and Energy, Southwest University, Chongqing, 400715, China.
Small methods
|September 17, 2025
概括
一种新的硫介导方法增强离子电池 (SIB) 的碳阳极,提高容量和性能. 这种具有成本效益的方法为先进的电池开发提供了可扩展的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 的商业化受到高性能,低成本碳阳极的需求的阻碍.
- 现有的方法通常需要高碳化温度,缺乏可扩展性.
研究的目的:
- 开发一种可扩展和具有成本效益的方法,用于生产SIB的高性能碳阳极.
- 研究硫中介合成对碳微观结构和储存特性的影响.
主要方法:
- 通过硫介导的固态方法,在基前体中创建3D交联聚合物网络.
- 与传统方法相比,碳化是在较低的温度 (≈1300°C) 进行的.
主要成果:
- 硫介导的方法阻止了石墨的转化,扩大了层间距离,并在碳材料中创造了封闭的孔隙.
- 储存能力从109到315mA hg-1显著增加,在低电压下超过81.3%的高原贡献.
- 与与氧相关的方法相比,该材料在较低的碳化温度下表现出优异的性能.
结论:
- 硫介导策略提供了一个可扩展和高效的途径,从低成本的中获得高性能碳阳极.
- 储存涉及一种联合吸附-间隙-孔隙填充机制,闭合的纳米孔对于低压性能至关重要.
- 这种方法为SIBs的商业化提供了有希望的进步.
相关概念视频
Preparation and Reactions of Sulfides
5.7K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
5.7K
Catalysis
30.1K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
30.1K
Electrophilic Aromatic Substitution: Sulfonation of Benzene
7.8K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
7.8K
Sulfur Assimilation
321
Sulfur is an essential element in biological systems, contributing to synthesizing key biomolecules, including amino acids such as cysteine and methionine, and cofactors such as coenzyme A and biotin. Microorganisms primarily assimilate sulfur as sulfate (SO₄²⁻) from the environment, which must undergo a series of biochemical transformations before it can be incorporated into cellular components. As sulfate is highly oxidized, it must undergo assimilatory sulfate reduction to...
321
Electrodeposition
1.3K
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
1.3K
Reduction of Alkenes: Catalytic Hydrogenation
13.9K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
13.9K


