设计用于复杂废水系统中Au(III) 吸附的新型乙烯-胺基功能化聚合物:选择性和可重复使用性
Yihui Wu1,2, Dawei Xiang1,2, Manying Zhu1,2
1School of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China.
The journal of physical chemistry. B
|September 17, 2025
概括
一种新的聚合物,MPPTD,有效地从废水中回收黄金 (Au ((III)). 这种可持续吸附剂显示出高容量和选择性,为黄金回收和环境保护提供了有前途的解决方案.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 从废水中回收黄金 (Au ((III)) 解决了环境污染问题.
- 缓解自然黄金资源的枯竭至关重要.
研究的目的:
- 合成和评估一种新型聚合物MPPTD,以实现高效的黄金回收.
- 调查MPPTD对Au的吸附机制和性能.
主要方法:
- 一种新型聚合物 (MPPTD) 与胺基和硫乙烯基组的合成.
- 吸附实验以确定容量,动力学和热力学.
- 使用 ζ-电位,XRD 和 XPS 进行表征,以阐明吸附机制.
主要成果:
- MPPTD显示出高吸附能力 (970.07毫克/克在318K,pH3下).
- 吸附遵循Redlich-Peterson和Elovich模型,表明混合化学吸附与内部扩散.
- 在5个循环后,MPPTD对Au (III) 具有很好的选择性,并保持了>81.39%的效率.
结论:
- MPPTD是一种高效,可持续和可重复使用的黄金回收吸附剂.
- 该研究强调了MPPTD在工业废水处理应用中的潜力.
相关概念视频
Ion Exchange
1.1K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.1K
Complexometric Titration: Ligands
2.2K
Different monodentate and polydentate ligands are used as complexing agents in complexometric titration reactions. The formation of complexes by mono- and bidentate ligands involves two or more intermediate steps, limiting their use as complexing agents. In comparison, polydentate ligands can form complexes with metal ions in a single-step process, facilitating sharper end points. This means polydentate ligands, such as amino carboxylic acid derivatives, are most commonly employed in...
2.2K
Factors Affecting Solubility
36.7K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
36.7K


