单价和多价金属电池阳极之间的对比
Yuanjian Li1, Sonal Kumar1, Gaoliang Yang1
1Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore, Republic of Singapore.
概括
单价和多价金属阳极为更好的离子电池提供了石墨的替代品. 建议使用稳定的金属阳极和固体电解质介面 (SEI) 来实现下一代储能.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 石墨阳极限制了离子电池的性能.
- 单价 (Li,Na,K) 和多价 (Mg,Ca,Al) 金属阳极具有前景.
- 了解它们的电化学行为对于进步至关重要.
研究的目的:
- 对比和对比单价金属阳极的电化学行为.
- 讨论常见的挑战,如不规则的沉积和不稳定的固体电解质界面 (SEI).
- 建议改进金属阳极电池的设计策略.
主要方法:
- 对非水性电解质的电化学行为进行审查.
- 分析与表面能量和离子电荷密度相关的挑战.
- 对电极,电解质和相间设计策略的评估.
主要成果:
- 发现了共同的挑战:不规则的金属沉积和不稳定的SEI.
- 由于表面能量和离子电荷密度的突出差异.
- 对于具有偏好的晶体方向和稳定的SEI的水平沉积金属提出的策略.
结论:
- 金属阳极为高能低成本电池提供优势.
- 实现具有结构均性的稳定经济实体是关键.
- 需要跨学科的洞察力来推进下一代金属阳极电池.
相关概念视频
Batteries and Fuel Cells
30.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.7K
Standard Electrode Potentials
49.9K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
49.9K
Bonding in Metals
52.0K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
52.0K
Complexation Equilibria: The Chelate Effect
1.2K
In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
1.2K
Metal-Ligand Bonds
24.0K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.0K
Voltaic/Galvanic Cells
63.0K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
63.0K


