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Updated: Jan 17, 2026

Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
一种新的红色 Ba3La2W2O12:Eu3+具有强烈的D0-7F4过渡和优异的热稳定性为白色LED
Fei Wang1,2,3, Huihui Chen4
1Key Laboratory of Traffic Information and Safety of Anhui Higher Education Institutes, Anhui Sanlian University, Hefei 230601, People's Republic of China. wangfchina@163.com.
基于Ba3La2W2O12:Eu3+的新型红色发射显示出优异的热稳定性和高量子效率,显著改善转换白色发光二极管 (pc-WLED).
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的光度是非常的低.
背景情况:
- 红色发光的高热稳定性对于先进的转换白色发光二极管 (pc-WLED) 是至关重要的.
- 受到eu3+兴奋剂的材料被广泛用于红色排放应用.
研究的目的:
- 为了合成和描述小说Ba3La2W2O12:Eu3+ (BLWO:Eu3+) 的红色.
- 评估它们的光学特性,热稳定性和适用于PC-WLED的适用性.
主要方法:
- 合成的高温固态反应.
- 用于晶体结构分析的X射线衍射.
- 光发光谱学用于确定辐射光谱和量子效率.
- 热稳定性测试. 热稳定性的测试.
- 一个原型PC-WLED设备的制造和测试.
主要成果:
- 成功合成了BLWO:Eu3+,在616nm时有强烈的红色发射 (5D0 → 7F2) 和显著的702nm发射 (5D0 → 7F4).
- 最佳的Eu3+度确定在0.06,通过四极-四极相互作用灭度.
- 实现了62.91%的高内部量子效率 (IQE) 和35.23%的外部量子效率 (EQE),具有出色的热稳定性.
- 制造的pc-WLED设备显示了温暖的白光 (CIE: (0.3453,0.3518)) 和高颜色染指数 (Ra) 的80.3.3.
结论:
- BLWO:0.06Eu3+体表现出优越的发光性能和热稳定性.
- 开发的是高性能pc-WLED应用的有希望的候选者.
- 这项研究强调了Ba3La2W2O12宿主对于高效的红色发射的潜力.
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