刚果红与MOF的相互作用促进了水中Cr (VI) 的特定检测

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Updated: Jan 17, 2026

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Xu-Hui Zhao¹, Rui-Dong Wang¹, Jun-Fu Man¹

¹Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education and Yunnan Province, Yunnan Characteristic Plant Extraction Laboratory Co., Ltd, School of Chemical Science and Technology, School of Pharmacy, Yunnan University, Kunming 650500, China.

Inorganic chemistry

|September 19, 2025

概括

新的金属有机框架 (MOF) 用刚果红色 (CR) 合成和修改. 由此产生的CR@MOF复合材料显示有毒Cr (VI) 离子的选择性光传感,为环境监测提供了潜力.

科学领域:

材料科学材料科学材料科学
化学化学化学
环境科学环境科学

背景情况:

金属有机框架 (MOF) 是具有可调节性质的先进多孔材料.
光传感为检测环境污染物提供了一种敏感的方法.
刚果红 (CR) 是一种可以加入到材料中的染料,以修改其特性.

研究的目的:

为了合成新的三维MOF (MOF-1-3).
调查刚果红 (CR) 对MOF-1-3的负载及其对光特性的影响.
评估CR@MOF-1-3复合材料在选择性检测Cr (VI) 离子方面的潜力.

主要方法:

合成了三种新的三维MOF (MOF-1-3).
将刚果红 (CR) 染料加载到合成的MOF上.
描述CR@MOF-1-3复合材料的光特性.
在Fe (III) 离子的存在下对Cr (VI) 离子的选择性识别的研究.

主要成果:

成功合成并确认MOF-1-3的化学稳定性和光.
在MOF-1-3中系统地调查CR加载行为和机制.
在CR加载后,CR@MOF-1-3复合材料的光特性发生显著变化.
通过CR@MOF-1-3对Cr (VI) 离子 (CrO4^2-和Cr2O7^2-) 的选择性识别,有效消除Fe (III) 干扰.

结论:

复合材料CR@MOF-1-3具有对Cr (VI) 离子的选择性光传感能力.
这些材料有望成为用于环境监测的多功能光传感平台.
该研究为设计基于MOF的光探针用于化学分析提供了指导.

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