在干燥过程中,单纤维棉纤维中纤维素微纤维的可逆和不可逆的结构变化
Hiroki Murase1, Kenichi Funaki2, Hiroyasu Masunaga3
1Department of Textile and Clothing, Faculty of Home Economics, Kyoritsu Women's University, 2-2-1 Hitotsubashi, Chiyoda-ku, Tokyo 101-8437, Japan.
Carbohydrate polymers
|September 19, 2025
概括
干燥棉纤维会导致纤维素微纤维的无形外发生不可逆转的变化,影响其纳米结构. 补水史是了解纤维素纤维的这些结构演变的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 生物物理学的生物物理.
背景情况:
- 纤维素微纤维是棉纤维的结构基础.
- 了解干燥过程中纤维素的结构动态对于纤维应用至关重要.
- 在纤维素微纤维结构中水分史的作用仍然不完全理解.
研究的目的:
- 研究在干燥过程中棉纤维中纤维素微纤维的结构演变.
- 要区分可逆和不可逆的结构变化.
- 为了阐明水化史对纤维素纳米级架构的影响.
主要方法:
- 同时使用同步射线辐射进行小角X射线散射 (SAXS) 和广角X射线散射 (WAXS).
- 系统地比较从未干燥的棉花 (NDC) 和重新浸泡的棉花 (RWC).
- 分析使用核心-外-圆柱体模型来推导结构参数.
主要成果:
- 从未干燥的棉花 (NDC) 与重新浸泡的棉花 (RWC) 相比,在纤维素微纤维周围呈现出更厚的无形外.
- 干燥减少了晶体的尺寸和结晶性,在重新湿时部分恢复.
- 无形外在干燥过程中经历不可逆转的密度和收缩.
结论:
- 水史极大地影响了纤维素微纤维素的纳米级架构.
- 棉纤维的干燥过程涉及不同的阶段,影响微纤维结构.
- 无形外的不可逆转变化是纤维素纤维干燥过程的一个关键结果.
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