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硫化聚3,4-乙烯二氧化 (PEDOTs) 的内在兴奋剂和静电复合

Hyunki Yeo1, Anush Singhal2, Alexandra Zele2

  • 1Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States.

ACS macro letters
|September 21, 2025
PubMed
概括

自吸附的合聚合物为导电混合物提供了简化加工. 硫化PEDOT衍生物中微妙的侧链变化显著影响导电性,即使在复杂化后也能实现高性能.

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Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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