在氧化温度和持续时间的合效应下,对煤孔结构变化的实验研究
Yaxian Yu1, Zhenya Zhang1,2, Song Kong3
1Zhejiang Key Laboratory of Intelligent Construction and Operation & Maintenance for Deep-Sea Foundations, Ningbo University of Technology Ningbo 315211 P. R. China zhangzhenya@nbut.edu.cn.
RSC advances
|September 24, 2025
概括
煤孔结构随着温度和时间的变化而动态发展. 增加加热通常会降低毛孔复杂性,影响毛孔体积和表面积分布,特别是在微孔中.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 煤孔结构对于能量储存和释放至关重要.
- 了解煤炭孔的热效应对于资源利用和安全至关重要.
研究的目的:
- 为了研究合温度-时间效应下的煤孔结构的演变.
- 用碎形理论量化描述孔隙结构异质性的方法.
主要方法:
- 编程温度油浴实验被用于处理煤样品.
- 低温吸附 (LTNA) 和BET理论分析了孔隙特性.
- FHH碎形理论量化了孔隙结构的异质性.
主要成果:
- 半孔体积减少,而微孔和巨孔体积显示热处理复杂的变化.
- 微孔表面积最初增加,然后减少;中孔和巨孔表面积呈现相反的趋势.
- 碎形尺寸 (D1>D2) 表示表面毛孔粗;温度上升使两种碎形尺寸都下降.
结论:
- 煤孔结构在合的热时间条件下经历了显著的演变.
- 温度和持续时间显著影响毛孔体积,表面积和碎形特征.
- 碎形分析提供了关于煤矿孔状网络复杂异质性的见解.
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