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Updated: Jan 17, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Published on: March 20, 2017

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合成桥替代的Bicyclo[1.1.1]Pentanes通过催化金属碳素插入到Bicyclo[1.1.0]Butanes中的

Shaopeng Liu1, Yongquan Ning1, Wei Song1

  • 1Department of Chemistry, Northeast Normal University, Changchun, 130024, China.

Angewandte Chemie (International ed. in English)
|September 25, 2025
PubMed
概括

研究人员开发了一种新方法来合成1,2,3-三替代双循环[1.1.1] (BCPs),使用金属碳素插入双循环[1.1.0] (BCBs) 中. 这种方法避免了危险的试剂,并提供了访问有价值的BCP支架.

关键词:
自行车[1.1.0]酸自行车[1.1.1]坦酸金属碳化合物金属碳化合物压力过大的分子.三基化酸盐 (Triftosylhydrazones) 是一种酸盐.

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