开发一种基于香糖改性煤灰的水泥防火材料,用于煤矿,具有更好的高温耐受性
Guolan Dou1,2,3, Peng Chen1,2,3, Menghan Wang1,2,3
1Key Laboratory of Gas and Fire Control for Coal Mines, China University of Mining and Technology, Xuzhou 221116, China.
Materials (Basel, Switzerland)
|September 27, 2025
概括
这项研究开发了一种低碳的煤灰飞混凝土材料,用于密封煤火. 添加桑坦 (XG) 提高了热稳定性和抗破裂性,但过量减少了性能.
科学领域:
- 材料科学 材料科学 材料科学
- 地质技术工程 地质技术工程
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤炭飞灰提出了处置的挑战,其在建筑材料中的利用是可取的.
- 开发低碳替代传统水泥材料的替代品对于环境可持续性至关重要.
- 煤炭火灾带来重大风险,需要有效的密封材料.
研究的目的:
- 为了合成和优化煤炭飞灰基的水泥材料用于煤炭防火.
- 为了研究香甘 (XG) 对开发材料特性的影响.
- 评估材料在热应力下的性能,并确定最佳的XG含量.
主要方法:
- 使用Box-Behnken设计的响应表面方法 (RSM) 用于配方优化.
- 设置时间,流动性和压力强度的表征.
- 在加热后评估热收缩和裂纹阻力.
- 分析由于XG结合而导致的微观结构变化.
主要成果:
- 实现了最佳配方:煤灰与前体比为0.65,活性剂模量为1.4,活性剂剂量为7.5%.
- 优化材料的初始/最终设置时间为26/31分钟,流动性为245毫米,7天强度为36.60MPa.
- 结合1重量%的XG,提高了压力强度 (1天: +15.44%,7天: +1.97%) 和增强了热收缩和裂纹抵抗.
- 较高的XG含量 (>1 wt.%) 导致由于凝网络中断导致压力强度和流动性降低.
结论:
- 开发了一种可行的低碳,基于煤炭飞灰的水泥密封材料.
- 赞坦有效地提高了材料的热性能和抗裂性能,高达1%的重量.
- 需要仔细控制XG含量,以平衡改善的热性能,同时保持机械强度和可加工性.
更多相关视频
11:07Preparation of Aligned Steel Fiber Reinforced Cementitious Composite and Its Flexural Behavior
Published on: June 27, 2018
11.6K
14:51An Available Technique for Preparation of New Cast MnCuNiFeZnAl Alloy with Superior Damping Capacity and High Service Temperature
Published on: September 23, 2018
7.4K
相关概念视频
Pozzolans
482
Pozzolans are siliceous or aluminous materials blended with Portland cement. They interact with the calcium hydroxide produced during the hydration of Portland cement and contribute to improved strength and durability of concrete. The pozzolanic activity, a measure of a pozzolan's effectiveness, is typically assessed using the strength activity index, as defined in ASTM C 618-93, which calculates the ratio of the compressive strength of cement mixtures with and without pozzolan.
Fly ash is...
Fly ash is...
482
Types of Cement II
389
Portland blast-furnace cement is made by blending Portland cement clinker with granulated blast-furnace slag, which accounts for 25 to 65 percent of the cement's weight. Despite its similarities to ordinary Portland (Type I) cement in terms of fineness and setting times, its early strength is lower, though it achieves comparable strength later on. It's particularly suited for mass concrete structures and marine environments due to its lower heat of hydration and superior sulfate...
389
Types of Cement I
348
Portland cement comes in several types, each with distinct properties and applications based on their chemical composition and hydration characteristics:
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
348
Additives and Fillers in Concrete
332
Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...
The...
332
Strength and Heat of Hydration
653
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
653
Hydration of Cement
815
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
815
