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未经修改的植物和废油作为PU地板粘合剂的功能添加剂:一项比较研究
Żaneta Ciastowicz1,2, Renata Pamuła2, Edyta Pęczek1,2
1Department of Applied Bioeconomy, Wrocław University of Environmental and Life Sciences, 37a Chełmońskiego Str., 51-630 Wroclaw, Poland.
Molecules (Basel, Switzerland)
|September 27, 2025
概括
这项研究发现,未经修改的植物油,包括麻油,菜油和向日油,可以在满足机械标准的同时以10%的重量加入到聚氨 (PU) 板粘合剂中. 这种方法避免了额外的加工步骤,减少了碳足迹.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续化学 可持续化学
背景情况:
- 聚氨 (PU) 粘合剂广泛用于地板应用.
- 对于可持续和环保的粘合剂配方的需求越来越大.
- 植物油为修改聚合物特性提供了潜在的可再生资源.
研究的目的:
- 评估用各种未经修改的植物油修改的聚氨木板粘合剂的性能.
- 为了比较这些配方的机械性能,无机液和挥发性有机化合物 (VOC) 排放.
- 评估使用反应性和非反应性油作为PU粘合剂的直接替代品或修饰剂的可行性.
主要方法:
- 在一个双组分PU粘合剂中加入10重%的反应性 (castor) 和非反应性 (麻,向日,亚麻,用于) 油.
- 根据EN ISO 17178.8.标准进行机械性能测试.
- 使用EN 12457-4.4的无机漏分析.
- 挥发性有机化合物选通过头空间气体染色学-质谱学 (HS-GC-MS).
主要成果:
- 所有的内部配方都符合EN ISO 17178的机械性能限制.
- 太阳花油表现出最高的剪切强度;油菜和麻油显示出稳定的拉伸性能.
- 使用的油配方显示出增加的可变性和增加的 (Zn) 和 (Sb) 出.
- HS-GC-MS分析没有为监管要求提供高可信度的VOC鉴定.
结论:
- 符合标准的性能可以在PU地板粘合剂中以10%的重量负载实现反应性和非反应性未经修改的油.
- 使用非反应性油的物理修饰可能足够,而像麻油这样的反应性油可能参与PU反应.
- 使用未经修改的油避免了额外的化学修改步骤,与衍生油相比,可能降低碳足迹.
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