相关实验视频

Updated: Jan 6, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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基基,化物和化物复合物:合成,表征和催化应用:基于大容量 bis-guanidine联体的中性和阴性基,化物和化物复合物:合成,表征和催化应用

Rajata Kumar Sahoo1, Sayantan Mukhopadhyay1, Sagrika Rajput1

  • 1School of Chemical Sciences, National Institute of Science Education and Research (NISER), Homi Bhabha National Institute (HBNI) Bhubaneswar, Odisha, 752050, India. snembenna@niser.ac.in.

Dalton transactions (Cambridge, England : 2003)
|September 29, 2025
PubMed
概括

这项研究使用 bis-guanidine 连接体合成了新型的复合物. 酸复合物在合成碳化合物中的蓝氨基乙醇中表现出催化活性.

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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex10:52

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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