在班克罗夫特破碎系统中,装有表面活性剂的微尺度滴滴凝聚
Yun Chen1, Negin Bahadori2, Cari S Dutcher1,3
1Department of Mechanical Engineering, University of Minnesota - Twin Cities, 111 Church Street SE, Minneapolis, MN 55455, USA. cdutcher@umn.edu.
Soft matter
|September 30, 2025
概括
乳液中的滴滴稳定性受粘度和表面活性剂度的影响. 实验显示,薄膜排水时间和表面活性剂水平之间存在令人惊的非单调关系,由马兰戈尼压力解释.
科学领域:
- 合体和表面科学科学
- 流体动力学 流体动力学
- 微流体学 微流体学
背景情况:
- 液-液滴乳液由表面活性剂稳定,降低表面张力.
- 滴滴稳定性也受到粘性和马兰戈尼应力的影响.
- 了解凝聚力学动态对于乳液应用至关重要.
研究的目的:
- 系统地研究微流体系统中的滴滴凝聚.
- 分析粘度比和表面活性剂度对凝聚的影响.
- 阐明表面活性剂驱动稳定的基本机制.
主要方法:
- 使用微流体斯托克斯陷进行受控滴滴凝聚实验.
- 滴状和连续相之间的粘度比率不同.
- 系统地改变了表面活性剂的度 (Triton X100,Glucopon 225DK).
主要成果:
- 较高的粘度比率 (>1) 抑制了滴滴凝聚.
- 较低的粘度比 (<1) 促进了滴滴凝聚.
- 观察到薄膜排水时间的非单调趋势随着表面活性剂度的增加,显示最初的增加,然后下降,然后是平稳.
结论:
- 粘度比显著影响滴滴凝聚,正如预期的那样.
- 非单调的薄膜排水时间依赖于表面活性剂度是一个关键的发现.
- 马兰戈尼数分析,考虑到时间尺度和压力比率,成功地解释了观察到的实验趋势.
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