在细分的微流中通过使用数字直线全息图的折射率测量进行流体组成分析
Paul Bresson1, Tamar Kurdadze1, Isaac Rodriguez-Ruiz2
1CEA, DES, ISEC, DMRC, Univ. Montpellier, Marcoule, Bagnols-sur-Cèze 30207, France.
Analytical chemistry
|September 30, 2025
概括
数字直线全息 (DIH) 测量水滴折射率在水电金的微流体. 这种技术可以在现场分析非吸收阶段,这对于回收过程至关重要.
科学领域:
- 光学计量学 在光学计量学
- 微流体学 微流体学
- 水电金术是指用水电金术进行金术.
背景情况:
- 传统的紫外线光谱对于分析液液提取中的非吸收相是无效的.
- 准确地在现场测量滴滴特性对于优化水力金回收过程至关重要.
- 现有的方法缺乏实时,多相系统中透明滴滴的非侵入性分析的能力.
研究的目的:
- 引入和验证数字直线全息 (DIH) 的新型应用,用于在现场测量透明液滴的折射率.
- 解决液体-液体提取系统中的分析差距.
- 为了能够同时确定细分微流体流中的滴滴大小和折射率.
主要方法:
- 开发一种定制的微流体装置,用于产生单分散滴.
- 实施DIH光学设置以捕捉滴滴衍射模式.
- 结合图像分析和洛伦兹-米理论,同时确定尺寸和折射率.
主要成果:
- 同时确定滴滴大小和折射率,精度为 Δn ∼ 10−2.2.
- 证明了与基板折射计的良好一致性,验证了DIH方法.
- 显示了适用于监测两个相的过程变量,如分散和连续相中的酸度.
结论:
- DIH提供了一种可行的方法,用于对微流体中的透明滴滴进行定量 in situ 折射率测量.
- 该技术适用于监测液体金液体提取中的关键过程变量.
- 该方法显示了扩展到吸收介质和复杂的多相系统的潜力,包括核燃料再加工和关键金属回收利用.
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