在自然坚果中普遍存在的室温光
Ruizhi Yang1, Hao Su1, Jiajun Song1
1Department of Chemical Physics, School of Chemistry and Materials Science, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China.
Journal of the American Chemical Society
|October 1, 2025
概括
由于分散的芳香营养物质,天然坚果表现出可持续的室温光 (RTP). 这一发现为RTP材料提供了清洁,丰富的替代品, 在数据存储和传感方面具有潜在应用.
科学领域:
- 材料科学
- 有机化学
- 生物物理
背景情况:
- 室温光 (RTP) 对于先进的应用至关重要,但通常依赖于基于化石燃料的材料.
- 人们对自然有机RTP越来越感兴趣,但记录的案例和对结构与财产关系的理解有限.
研究的目的:
- 识别和描述具有室温光 (RTP) 的天然坚果.
- 阐明基于坚果的RTP背后的分子起源和机制.
- 探索坚果作为RTP材料的可持续来源的潜力.
主要方法:
- 在环境条件下对各种天然坚果的RTP特性进行全面分析.
- 从内在营养物质确定RTP的分子起源的光谱研究.
- 使用微量多芳调整RTP特性的调制研究.
主要成果:
- 天然坚果在室温下表现出数秒长的RTP,这取决于激发波长和成分.
- RTP来源于坚果母体内的低度芳香维生素,核基和氨基酸.
- RTP覆盖了广泛的光谱 (<400至>700 nm),颜色可以通过激发能量和微量光素调节.
结论:
- 自然坚果是清洁的RTP材料的可持续和丰富储备.
- 生物质和多种芳香营养素之间的协同作用控制了激发依赖的RTP.
- 基于坚果的RTP为多层信息存储等应用开发具有成本效益的大型发光材料提供了潜力.
相关概念视频
Photoluminescence: Applications
1.0K
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
1.0K
Variables Affecting Phosphorescence and Fluorescence
1.3K
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
1.3K
Photoluminescence: Fluorescence and Phosphorescence
3.5K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
3.5K
Fluorescence and Phosphorescence: Instrumentation
1.4K
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
1.4K
The Phosphorus Cycle
43.6K
Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
43.6K


