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相关概念视频

Colloidal precipitates01:09

Colloidal precipitates

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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Colloids03:22

Colloids

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Colloids and Suspensions01:17

Colloids and Suspensions

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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Coagulation01:06

Coagulation

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Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
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Bioavailability Enhancement: Drug Stability Enhancement and GI Retention01:05

Bioavailability Enhancement: Drug Stability Enhancement and GI Retention

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Body:Improving a drug's stability in the gastrointestinal (GI) tract is paramount for enhancing its bioavailability and therapeutic effectiveness. Various strategies are employed to protect the drug from the harsh gastric milieu and to ensure its release and absorption at the desired site within the GI tract.Polymer coatings are one such method used to shield drugs from the stomach's acidic environment. By preventing premature drug release, these coatings improve the bioavailability of unstable...
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Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

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The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
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Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst
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在RAFT种子乳液聚合过程中增强体稳定性

Zongying Hu1, Ruilong Zhang1, Hanying Zhao1

  • 1Key Laboratory of Functional Polymer Materials, Ministry of Education, College of Chemistry, Nankai University, Tianjin 300071, China.

Langmuir : the ACS journal of surfaces and colloids
|October 3, 2025
PubMed
概括

这项研究提高了可逆添加-碎片化链转移 (RAFT) 乳液聚合物的颗粒稳定性. 在种子颗粒上移植Zwitterionic聚合物块,提高乳的稳定性,并使新的材料特性成为可能.

科学领域:

  • 聚合物化学 聚合物化学
  • 材料科学 材料科学 材料科学
  • 纳米技术 纳米技术

背景情况:

  • 可逆添加碎片化链转移 (RAFT) 乳液聚合是粒子设计的关键.
  • 在RAFT乳液聚合过程中的一个挑战是,随着颗粒的生长,保持颗粒稳定性.
  • 在不断增长的乳颗粒上降低稳定剂密度会导致聚合.

研究的目的:

  • 使用RAFT在种子乳液聚合过程中提高颗粒稳定性.
  • 为了合成具有可移植功能的核心外种子颗粒.
  • 为了研究zwitterionic聚合物块在粒子表面上的特性.

主要方法:

  • 通过RAFT乳液聚合,制备聚甲基酸) 核心和聚甲基酸) 贝种子粒子.
  • 用电子转移原子转移基聚合物生成的激活剂将zwitterionic poly(3-dimethyl(methacryloyloxyethyl) -ammonium propanesulfonate) 块移植到种子颗粒上.
  • 随后的RAFT用功能化的种子颗粒对n-丁烯酸盐进行种子乳液聚合.

主要成果:

  • 在种子聚合过程中表现出增强的粒子稳定性.
  • 通过移植的zwitterionic聚合物块成功合成了核心外颗粒.

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Synthesis and Characterization of Supramolecular Colloids

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  • 研究了zwitterionic块的高临界溶液温度 (UCST) 行为和盐反应.
  • 结论:

    • 将zwitterionic块移植到RAFT合成的种子颗粒上,显著提高了乳的稳定性.
    • 功能化的粒子表现出可调节的特性,如UCST行为和盐的反应性.
    • 这种方法为乳液聚合过程中的高级粒子设计提供了一个有希望的策略.