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将Electro Fenton与吸附过程相结合,用于处理石油炼油厂的废水

Ali N Kassob¹, Ali H Abbar², Abdullah Y Ghjeer¹

¹Chemical Engineering Department, College of Engineering, University of Al-Qadisiyah, Al-Diwaniyah, Iraq.

Water environment research : a research publication of the Water Environment Federation

|October 4, 2025

概括

这项研究结合了电-芬顿 (EF) 和活性炭 (AC) 吸附来处理石油炼油厂废水,实现了高化学氧气需求 (COD) 的去除. 与单独使用EF相比,EF+AC过程显示出更高的效率和更低的能耗.

科学领域:

环境化学环境化学
水处理技术水处理技术
化学工程是化学工程的重要组成部分.

背景情况:

由于高化学氧气需求 (COD),石油炼油厂的废水给环境带来了重大挑战.
传统的治疗方法可能不足以完全消除COD,需要先进的氧化过程.
电-芬顿 (EF) 工艺和活性炭 (AC) 吸附是废水整治的有希望的技术.

研究的目的:

研究Fenton电气和活性炭吸附 (EF+AC) 过程的组合,以消除石油炼油厂废水中的COD.
使用响应表面方法 (RSM) 优化EF过程参数,采用盒式设计 (BBD).
使用中央复合设计 (CCD) 来优化EF+AC过程参数.

主要方法:

电-芬顿 (EF) 工艺使用RSM-BBD优化了FeSO4度,电流密度和电解时间.
结合EF+AC过程被优化为活性炭 (AC) 包装水平和时间在恒定的EF参数使用RSM-CCD.
差异分析 (ANOVA) 用于确定过程参数的意义.

主要成果:

在最佳条件下,EF工艺实现了99.06%的COD去除:85.12分钟的电解,25mA/cm2的电流密度和1.335mM FeSO4.4.
EF+AC工艺实现了98.77%的COD去除,92%的AC包装和85分钟的工艺时间,仅消耗0.91千瓦时/千克COD.
与单独使用EF工艺相比,EF+AC工艺的能耗显著降低,硫酸铁剂量减少.

结论:

结合的EF+AC工艺在去除石油炼油厂废水中的COD方面非常有效.
EF+AC流程为独立的EF流程提供了一个更节能,更节约资源的替代方案.
这种综合方法为工业废水处理提供了可行和可持续的解决方案.

关键词:

清除COD的使用方法活性炭活性炭的使用方法吸附吸附是一种吸附.电力-芬顿技术的技术石墨烯酸石墨是一种石墨.石油炼油厂的废水石油炼油厂的废水响应表面方法的方法.

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