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Updated: Jan 16, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
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在精确调节和结构-活性关系下合成含终结的甲

Kexuan Li1, Xiao Song2, Qianqian Zhao2

  • 1Xi'an Key Laboratory of Advanced Photo-electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi'an 710123, P.R. China.

The Journal of organic chemistry
|October 4, 2025
PubMed
概括

研究人员通过将原子添加到phenanthroimidazole衍生物中来合成了新的混合本地和电荷转移 (HLCT) 分子. 这种修改增强了光发光的量子产量和缩小了光谱峰值,优化了光物理性质.

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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