从生物固体改变的土壤中运输和多基物质 (PFAS):一种实验和数值方法
Alonso Doria-Manzur1, Evan P Gray1, Summer S Streets2
1Civil Environmental and Construction Engineering, Texas Tech University, USA.
Water research
|October 4, 2025
概括
和多醇基物质 (PFAS) 存在于应用于土壤的生物固体中. 这项研究表明,PFAS漏到地下水是缓慢的,但随着时间的推移而显著,需要对土地应用地点进行全面的风险评估.
科学领域:
- 环境化学环境化学
- 土壤科学 土壤科学
- 环境工程 环境工程
背景情况:
- 和多醇基物质 (PFAS) 是常规废水处理不能去除的持久性有机污染物.
- 废水处理的副产品生物固体含有累积的PFAS,经常应用于农田.
- 不过,PFAS从生物固体修饰土壤中出地下水的泄漏行为和运输机制尚不清楚.
研究的目的:
- 研究PFAS从生物固体修饰土壤中的运输机制和长期泄漏潜力.
- 在现场条件下模拟特定PFAS ( perfluorooctanoic acid和 perfluorooctane sulfonate) 进入地下水的运动.
- 在考虑PFAS污染的情况下,为土地应用生物固体提供最佳管理实践的信息.
主要方法:
- 市政生物固体与土壤混合,并装入和的流通柱.
- 生物固体,修改土壤和柱体化剂使用目标分析,总可氧化前体 (TOP) 测定和嫌疑人查进行了分析.
- 用HYDRUS 1-D建模和列数据,以确定长期漏模拟的运输参数.
主要成果:
- 大多数PFAS前体 (>65%) 在浸出实验后仍然被吸收到生物固体修改土壤中.
- 化剂中的调动PFAS主要是短链前体 (≤C7).
- 液体1D建模表明,在和条件下,PFAS从修改过的土壤中脱落的速度是有限的,长期模拟预测PFAS在40年后到达地下水.
结论:
- 在和条件下,PFAS从生物固体修改土壤入地下水是一个缓慢的,速度有限的过程.
- 对生物固体的长期土地应用可能会导致地下水中可检测到的PFAS度.
- 最佳管理实践应考虑多路径暴露,包括移动PFAS的土壤到地下水路径,以及不太移动PFAS的其他路径.
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