揭示滴滴形态:实时粘度映射揭示了干燥聚合物溶液的物理原理
Elham Mirzahossein1, Marion Grzelka2, Daniel Bonn1
1Van der Waals-Zeeman Institute, Institute of Physics, University of Amsterdam, 1098XH Amsterdam, The Netherlands. d.bonn@uva.nl.
Soft matter
|October 6, 2025
概括
聚合物滴滴的干燥形成了类似凝的皮肤,决定了最终的形状. 皮肤厚度和均性,实时测量,确定滴滴形态,如咖啡环和墨西哥帽子.
科学领域:
- 流体动力学 流体动力学
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
背景情况:
- 聚合物溶液滴滴干燥导致不同的形态.
- 在蒸汽/液体接口处的凝状皮肤会影响滴滴的形状.
- 皮肤形成在确定最终滴水结构中的确切作用尚未完全理解.
研究的目的:
- 为了研究聚合物皮肤形成对干燥期间滴滴形态的影响.
- 量化皮肤特性与最终滴滴结构之间的关系.
- 为各种应用中控制沉积模式提供见解.
主要方法:
- 使用了具有经典流体动力学的创新光技术.
- 采用粘度敏感分子旋转器进行实时,空间分辨率的粘度测量.
- 在相同的环境条件下,研究了带有定针接触线的滴,只在相同的环境条件下改变初始接触角度.
主要成果:
- 皮肤厚度和空间不均性被确定为最终滴水形状的关键决定因素.
- 观察到三种不同的形态:咖啡环 (接触角~30°),墨西哥帽子 (接触角~55°) 和穿透的扣扣形状 (接触角~110°).
- 形态变化与皮肤厚度的突然变化直接相关,皮肤形成始于较低接触角的接触线.
结论:
- 该研究提供了对聚合物液滴干燥现象的全面了解.
- 结果与理论预测一致并扩展了理论预测,弥合了微观皮肤动态和宏观滴滴行为.
- 为控制喷墨印刷和生物医学试验等应用中的沉积模式提供了一个新的范式.
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