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Updated: Jan 15, 2026

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调节跨系统交叉到三重刺激子中的sp3功能化 (6,5) 碳纳米管通过缺陷密度和功能组

J Alejandro de Sousa1,2, Simon Settele3, Timur Biktagirov4

  • 1Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), 08193 Bellaterra, Spain.

ACS nano
|October 7, 2025
PubMed
概括

具有sp3缺陷的单壁碳纳米管 (SWCNTs) 的功能化改变了三重刺激子 (TE) 的行为. 这种缺陷工程控制TE动态,使量子传感和基于旋转的光电子技术的应用成为可能.

关键词:
在 PTM 激素中.跨系统交叉路口的交叉路口.通过光学检测到的磁共振.有机色彩中心有机色彩中心单壁碳纳米管是一种单壁碳纳米管.在 sp3 中存在缺陷.三重的激发子激发子

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Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the involved orbitals. The...
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