识别一个活跃的中间体和监测O─O键形成在水氧化由(III) -TAML复合体

Deesha D Malik1, Yong-Min Lee1, Shunichi Fukuzumi1

  • 1Department of Chemistry and Nano Science, Ewha Womans University, Seoul, 03760, South Korea.

概括

一个-TAML催化剂使用单电子氧化剂有效氧化水. 它的反应性由氧化还原位本地化控制,以联体为中心的复合体比以金属为中心的复合体活跃得多.

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