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Updated: Jan 15, 2026

Preparation and Use of Samarium Diiodide SmI2 in Organic Synthesis: The Mechanistic Role of HMPA and NiII Salts in the Samarium Barbier Reaction
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Published on: February 4, 2013

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合成和Yb和Sm反向三明治阵地复合物的活性

Sandeep Kumar Thakur1, Jens Langer1, Sjoerd Harder1

  • 1Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 1, 91058, Erlangen, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)
|October 8, 2025
PubMed
概括

稀土金属逆三明治复合体表现出独特的反应性. 伊特复合物反应广泛,而复合物显示有选择性的反应性,使新的 (II) 和 (III) 复合物成为可能.

关键词:
相反的三明治复合体兰他化物 兰他化物反应性反应性是指反应性.撒玛利亚 (Samararium) 是一个在此之前,它被认为是 ytterbium .

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