用于基于GAP的配方的能量增塑剂与ADN:一个酸甲的兼容性和性能评估
Patrick Lieber1, Uwe Schaller1, Thomas M Klapötke2
1Fraunhofer Institute for Chemical Technology Joseph-von-Fraunhofer-Str. 7 76327 Pfinztal Germany patrick.lieber@ict.fraunhofer.de.
RSC advances
|October 8, 2025
概括
一种新的能量增塑剂,NFPEG3N3,通过增强特定冲动来提高推进剂性能. 虽然与大多数组件兼容,但其与氨基丁胺 (DNA) 的长期热稳定性需要进一步研究.
科学领域:
- 能量材料科学 能量材料科学
- 聚合物化学 聚合物化学
- 推进剂的配方 推进剂的配方
背景情况:
- 甘酸聚合物 (GAP) 二醇是一种具有高形成度的有能结合剂,在与氨基丁胺 (ADN) 结合时提供良好的性能.
- 由于GAP的机械性能不佳,因此需要塑化,以提高其玻璃过渡温度.
- 能量增塑剂可以同时增强推进剂配方的机械和能量特性.
研究的目的:
- 评估一种新型的化基能量增塑剂NFPEG3N3与主要推进剂配方成分的兼容性.
- 评估NFPEG3N3对基于GAP的推进剂的能量和弹道性能的影响.
主要方法:
- 热流微热量计 (HFMC) 和热重量计 (TG) 用于根据STANAG 4147.7评估兼容性.
- 测试了NFPEG3N3的兼容性与甘酸聚合物 (GAP) 二醇,HMX,Desmodur N100和氨基丁胺 (DNA).
- 进行了性能计算,以确定NFPEG3N3对体积特异性脉冲和氧气平衡的影响.
主要成果:
- NFPEG3N3与GAP二醇,HMX和Desmodur N100的兼容性得到了证明.
- 该NFPEG3N3-DNA混合物通过了HFMC测试,但没有TG,这表明潜在的长期热稳定性问题.
- 在复合推进剂中用NFPEG3N3取代15 wt%的GAP,将体积特异性冲动增加了77 N s dm-3 .
结论:
- 对于大多数GAP推进剂组件来说,NFPEG3N3是一种兼容的能量增塑剂,显著提高了性能指标.
- 需要进一步的研究来解决NFPEG3N3在长期应用中与ADN结合的热稳定性.
- 与使用Bu-NENA相比,含NFPEG3N3的配方在氧气平衡和体积特异性冲动方面具有优势.
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