一个正方形平面铜-诺夫素协调复合物的合成和结构
Abdusamat Rasulov1, Batirbay Torambetov2, Jabbor Suyunov3
1Termez University of Economics and Service, 41B Farovon St, Termiz, 190111, Uzbekistan.
概括
使用诺夫洛克萨 (NF) 合成了一种新的铜(II) 协调复合物. 这个复合体表现出独特的超分子相互作用,包括键和π-π堆叠,形成柱状组件.
科学领域:
- 协调化学 协调化学
- 材料科学 材料科学 材料科学
- 晶体学 晶体学是指结晶学.
背景情况:
- 诺夫洛克萨 (NF) 是一种具有已知的抗菌性能的诺基诺抗生素.
- 涉及铜离子的协调复合体可以表现出不同的结构和电子性质.
- 了解超分子相互作用对于设计新材料至关重要.
研究的目的:
- 合成和表征一个新的协调复合体的铜 (II) 与norfloxacin.
- 为了研究合成复合物的晶体结构和超分子组合.
- 量化控制晶体包装的分子间力量.
主要方法:
- 使用诺弗洛素和铜酸三水合物合成铜 (II) - 诺弗洛素复合物.
- 单晶X射线衍射以确定分子和晶体结构.
- 希尔什菲尔德表面分析和二维指纹图为分析超分子相互作用.
主要成果:
- 协调复合物bis-[4-[03-carboxyl-ato-1-ethyl-6-fluoro-4-oxo-1,4-dihydro-quinolin-7-yl) piperazin-1-ium-κ2 O3,O4]铜(II) 丁酸盐, [Cu(C16H18FN3O3) ]2](NO3) 2已成功合成. 这种复合物是酸盐,酸盐,酸盐,酸盐,酸盐,酸盐.
- 晶体结构揭示了通过氧原子与铜(II) 离子协调的zwitterionicnorfloxacin连接物.
- 沿 b 轴的超分子组装由 π-π 堆叠,N-HO,C-HF 键和短 FF 相互作用促进.
结论:
- 合成的铜 (II) 复合体表现出有趣的超分子特征.
- 该研究提供了关于分子间力量在柱状结构形成中的作用的见解.
- 希尔什菲尔德分析有效量化了各种相互作用对晶体包装的贡献.
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