不钢在密集的CO2大气中的界面张力和临界表面张力
Aymeric Fabien1, Elisabeth Badens1, Guillaume Lefebvre2
1Aix Marseille Univ, CNRS, Centrale Med, and M2P2, F-13013 Marseille, France.
Langmuir : the ACS journal of surfaces and colloids
|October 9, 2025
概括
在高压和高温下测量了不钢/CO2接口的界面张力. 临界表面张力和界面张力随着压力而下降,与CO2相关.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 地质科学是地球科学.
背景情况:
- 不钢/二氧化碳系统的接口特性对于地质碳捕获和增强石油回收至关重要.
- 这些接口还没有得到充分的研究,特别是在工业应用中相关的高压和高温下.
研究的目的:
- 为了确定不钢/CO2接口的临界表面张力 (γC) 和界面张力 (γSF).
- 研究压力和温度对这些界面特性的影响.
主要方法:
- 使用Zisman图表来确定临界表面张力 (γC).
- 采用古德理论,计算分子相互作用参数,以确定界面张力 (γSF).
- 在316和316L不钢在0.1到15.1MPa的密度CO2下以及在313K和333K下进行测量.
主要成果:
- 临界表面张力 (γC) 和界面张力 (γSF) 都随着压力增加而下降.
- 温度对界面特性有更复杂的影响.
- 观察到界面特性与CO2的热力学状态之间的相关性,与Widom线相关.
结论:
- 不钢/二氧化碳系统的接口特性是压力依赖的.
- 对于316和316L不钢的结果相似,支持它们对一般的奥氏体不钢的适用性.
- 这些发现为涉及超临界CO2和不钢接口的应用提供了关键数据.
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