在离子电池中,用于高稳定性和快充O3型阴极的协同Cu/Ca双注策略
Jing Wu1, Wenbo Zhou1, Shu Zhang1
1Frontiers Science Center for New Organic Matter, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), State Key Laboratory of Advanced Chemical Power Sources, College of Chemistry, Nankai University, Tianjin, 300071, China.
Angewandte Chemie (International ed. in English)
|October 9, 2025
概括
将铜和离子引入O3型分层氧化物阴极可以提高离子电池的性能. 这种双重兴奋剂改善了离子运输和结构稳定性,使更快的充电和更长的循环寿命成为先进的能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- O3 型层氧化物为离子电池提供高特异性容量.
- 它们的实际应用受到缓慢的动力学和差的层间稳定性所阻碍,限制了快速充电和循环性能.
研究的目的:
- 为了提高O3型分层氧化物阴极的快速充电和长周期性能.
- 通过与Cu2+和Ca2+的协同兴奋剂实现有针对性的层间调节.
主要方法:
- 将Cu2+引入过渡金属 (TM) 层,并将Ca2+引入金属 (AM) 层.
- 使用扫描传输电子显微镜 (STEM) 和密度函数理论 (DFT) 的计算.
- 使用现场X射线衍射 (XRD) 进行结构分析.
主要成果:
- 2+兴奋剂扩大了离子运输通道,并抑制了Na+/空缺排序.
- Ca2+ 兴奋剂减轻了体积变化,并保持了结构完整性,减少了晶格应力.
- 实现了高速率 (86.02 mAh g-1 在10 C) 和延长周期寿命 (300 个周期后80.64%的保留).
结论:
- 对离子运输和晶格稳定的协同调节对于高性能离子电池阴极至关重要.
- 这种兴奋剂策略为设计先进的O3型分层氧化物阴极材料提供了新的途径.
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