在核事故后,牛奶中90Sr污染的高效量化
Q Rogliardo1, A Kanellakopoulos1, H Corcelle1
1Nuclear Physics & Chemistry Laboratories, HEPIA HES-SO, University of Applied Sciences and Arts Western Switzerland, Rue de la Prairie 4, Geneva, 1202, Switzerland.
概括
一种新方法使用冷干燥,化和染色学有效量化牛奶中的-90 (90Sr). 这一可靠的协议确保了核事故后食品中放射性污染的准确监测.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 放射化学 放射化学是指辐射化学.
背景情况:
- 牛奶中-90 (90Sr) 污染是一个重大问题,因为它具有放射性毒性和倾向于在骨中积累.
- 对食品矩阵中90Sr的准确和敏感的监测对于公共卫生和核应急响应至关重要.
研究的目的:
- 开发和验证一个高效的协议,用于定量牛奶中的90Sr.
- 将开发的方法的性能与现有的分析技术进行比较.
主要方法:
- 结合冷干燥,高温烧焦,离子交换色谱学和液体闪光光谱学 (LSC).
- 使用经过认证的参考牛奶样本进行验证,并与离心法和Dowex树脂方法进行比较.
- 评估化学产量,最小可检测活性 (MDA) 和回收率.
主要成果:
- 实现了100 ± 2%的高化学产量和0.33 Bq/L的低MDA.
- 与传统方法 (例如,瓜林的方法,多威克斯树脂) 相比,证明了优越的回收和有机物质消除.
- 通过实验室间比较证实了方法的稳定性,并观察到90Sr和90Y之间的世俗平衡.
结论:
- 开发的协议提供了一种高效,可靠和敏感的方法,用于牛奶中的90Sr量化.
- 该方法适用于常规辐射监测,并在核紧急情况下有效.
- 未来的研究应该将该协议的适用性扩展到各种食品矩阵.
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