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相关概念视频

Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

48.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
48.6K
Ionic Crystal Structures02:42

Ionic Crystal Structures

16.8K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.8K
Weak Acid Solutions04:02

Weak Acid Solutions

42.2K
Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of dissolved molecules in their original form and generating a relatively small amount of hydronium ions. Weak acids are commonly encountered in nature, being the substances partly responsible for the tangy taste of citrus fruits, the stinging sensation of insect bites, and the unpleasant smells associated with body odor. A familiar example of a...
42.2K
Formation of Complex Ions03:45

Formation of Complex Ions

25.7K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
25.7K
Acid Halides to Alcohols: LiAlH4 Reduction01:19

Acid Halides to Alcohols: LiAlH4 Reduction

3.8K
Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
3.8K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

26.5K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
26.5K

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相关实验视频

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Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
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离子点缺陷化物改善 (所有) 固态电池中的反应动力学

Seong Hee Jeong1, Seungun Shin2, Dongil Kim1

  • 1Department of Materials Science and Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin 17104, Republic of Korea.

ACS nano
|October 10, 2025
PubMed
概括

研究人员使用Li3+xAl1-x/3F6涂层开发了一种阴离子缺陷概念,以稳定离子电池 (LIB) 和全固态电池 (ASSB) 中的富含的阴极材料 (NCM),提高性能和耐用性.

关键词:
DFT计算的计算方法所有固态电池都是固态电池.阴阳点缺陷是因为阴阳点缺陷.涂层涂层是一种涂层.接口 接口 接口 接口 接口离子导电性的离子导电性

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 电池技术 电池技术

背景情况:

  • 富含的正极材料 (NCM) 为离子电池 (LIB) 和全固态电池 (ASSB) 提供高容量.
  • 在NCM和电解质之间的界面副作用会导致电阻增加和容量色,限制实际应用.
  • 控制界面反应对于开发高能LIB和ASSB至关重要.

研究的目的:

  • 为稳定NCM阴极提出并实施一个电离子缺陷概念.
  • 减少界面阻力,提高LIB和ASSB的结构稳定性.
  • 改进NCM阴极的电化学性能和循环性能.

主要方法:

  • 基于阴离子缺陷概念的Li3+xAl1-x/3F6涂层模型的开发.
  • 在NCM阴极上应用Li3.3Al0.9F6涂层.
  • 在各种条件下 (高温,高压) 对涂层组成对可逆性和界面稳定性的影响的研究.

主要成果:

  • 3.3Al0.9F6涂层具有高离子导电性和电压稳定性.
  • 在液体和固体电解质接口上有效控制接口副作用.
  • 显著降低界面电阻,改善NCM阴极的循环性能.

结论:

  • 阴离子缺陷概念成功地提高了NCM阴极的界面稳定性和电化学性能.
  • 3.3Al0.9F6涂层有助于实现高能LIB和ASSB.
  • 这种方法为开发用于先进电池应用的高度稳定的正极材料提供了途径.