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Updated: Jan 15, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Published on: July 27, 2022

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催化化中的异金属合作性:来自Rh (I) -Ga (III) 复合物的洞察力

Omar Jorge García-de-Jesus1, Alexander Mondragón-Díaz1, Bruno Donnadieu1

  • 1Department of Chemistry, Mississippi State University, Box 9573, Mississippi State, Mississippi 39762, United States.

Inorganic chemistry
|October 10, 2025
PubMed
概括

这项研究表明,Z型Rh(I) -Ga(III) 复合物与Rh-Ga西格玛键增强化催化. 复合物[Rh{MeGa(OPy-6-Me) 2}(C2H4) Me] (14) 在烯化中表现出优异的活性.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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