高密度冰在室温下通过冰XI一期的多个结融化路径
Yun-Hee Lee1, Jin Kyun Kim1, Yong-Jae Kim1,2
1Frontier of Extreme Physics, Space Metrology Group, Korea Research Institute of Standards and Science, Daejeon, Republic of Korea.
Nature materials
|October 10, 2025
概括
研究人员发现了室温超压缩水的多个结融化途径,揭示了像冰XXI.冰这样的新型转移稳定的冰相. 这挑战了以前关于在更高温度下形成冰的假设.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 地质物理学 地质物理学
背景情况:
- 由于缓慢的动力学,通常在低温下研究转化稳定的冰相.
- 在室温或高温下,冰相的多样性不太预期.
- 了解水在压力下的行为对于各种科学领域至关重要.
研究的目的:
- 为了研究在室温下超压缩水的相变.
- 在非低温条件下识别潜在的转稳冰阶段及其过渡途径.
- 探索水在极端压力下的结构演变.
主要方法:
- 在高压实验中使用动态钻石芯.
- 使用X射线自由电子激光 (XFEL) 技术进行结构分析.
- 在室温和高压下分析水的冷融化路径.
主要成果:
- 在室温的超压缩水中,在冰VI的压力区域内,证明了多种结融化途径.
- 发现了一个新的转移稳定的冰相,冰XXI (身体中心四角形结构,I4̄2d).
- 观察到冰VI的压力范围内存在金属稳定的冰VII,与新发现的冰XXI一起.
- 确定了从高密度水到非常高密度水的结构演变,作为这些多种途径的驱动因素.
结论:
- 在超压缩下,在室温下水存在多个过渡途径和转移稳定的冰相.
- 冰XXI和转移稳定的冰VII的发现扩大了已知的水相图.
- 这些发现为发现其他转移稳定的冰相和高温过渡途径开辟了新的途径.
更多相关视频
相关概念视频
Phase Transitions: Melting and Freezing
14.6K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
14.6K
Phase Transitions: Sublimation and Deposition
19.6K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
19.6K
Phase Changes
5.2K
Phase transitions play an important theoretical and practical role in the study of heat flow. In melting or fusion, a solid turns into a liquid; the opposite process is freezing. In evaporation, a liquid turns into a gas; the opposite process is condensation.
A substance melts or freezes at a temperature called its melting point and boils or condenses at its boiling point. These temperatures depend on pressure. High pressure favors the denser form of the substance, so typically, high pressure...
A substance melts or freezes at a temperature called its melting point and boils or condenses at its boiling point. These temperatures depend on pressure. High pressure favors the denser form of the substance, so typically, high pressure...
5.2K
Heating and Cooling Curves
26.5K
When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
26.5K
Phase Transitions: Vaporization and Condensation
20.6K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
20.6K
States of Water
56.0K
Water exists in any one of the three classical states: solid (ice), liquid (water), and gas (steam or water vapor). The state of water depends on i) the intermolecular forces that draw molecules together and ii) the kinetic energy that leads to movements that pull them apart.
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
56.0K


