不同源在斯特鲁维特恢复期间对四环素迁移的影响
Lixia Qiu1, Degui Gao1, Chenghui Yan1
1Water Research Center, Tsinghua Shenzhen International Graduate School, Tsinghua, Shenzhen, 518055, China.
Journal of environmental management
|October 12, 2025
概括
这项研究表明,大尺寸合金是恢复 (P) 作为 struvite 的最佳来源,在最终产品中显著减少像四环素 (TC) 这样的抗生素残留物. 这种方法还可以降低成本,因为不需要调整pH值.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 可持续农业 可持续农业
背景情况:
- 斯特鲁维特结晶是从废水中回收的关键方法,产生有价值的肥料.
- 在回收的 struvite 中的抗生素残留物构成生态风险,需要对其减轻的研究.
- 不同 (Mg) 来源对斯特鲁维特恢复期间抗生素积累的影响尚不清楚.
研究的目的:
- 研究各种Mg来源,Mg剂量,废水盐度和四环素 (TC) 度对 struvite 生产的影响.
- 分析在回收过程中中struvite晶体中TC的迁移行为和积累.
- 确定最佳条件和Mg来源,以最大限度地减少回收 struvite 中的抗生素残留物.
主要方法:
- 系统评估不同的Mg来源:MgCl2,MgO,小尺寸Mg合金和大尺寸Mg合金.
- 有控制的实验改变了Mg剂量,废水盐度和初始TC度 (20和200μg/L).
- 在得到的斯特鲁维特晶体中量化PO43−-P回收效率和TC含量.
主要成果:
- 回收效率因源而异,从7.28% (小型合金) 到98.81% (MgCl2) 有显著差异.
- 斯特鲁维特中的TC含量与初始TC度正相关,并受到Mg来源和盐度的影响.
- 大尺寸的Mg合金导致TC含量最低 (2.4553.04μg/g在200μg/LTC) 并消除了pH调整的需要.
结论:
- 合金,特别是大尺寸的合金,是 struvite 恢复的非常有前途的来源,最大限度地减少了抗生素污染.
- 选择Mg源对回收效率和四环素的共同沉都产生了重大影响.
- 使用Mg合金提供了一种具有成本效益和环境安全性的方法,用于从牲畜废水中回收.
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