在催化回氧反应中迁移Cu-Pd双金属粒子的振荡动力学
Qiao Zhao1,2, Shuhui Liu3, Zhenghao Jia1,4
1State Key Laboratory of Catalysis, Division of Energy Research Resources, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
The journal of physical chemistry letters
|October 13, 2025
概括
铜纳米粒子在氧化还原反应期间表现出非平衡振荡动力学和迁移. 这种运动是由铜氧化还原反应和异步反应剂扩散驱动的,为催化剂粗化提供了洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
- 纳米技术纳米技术
背景情况:
- 纳米粒子 (NP) 在催化回氧反应中经历重建和迁移.
- 了解NP重组机制对于控制反应动力学和防止催化剂粗化至关重要.
研究的目的:
- 研究铜 (Cu-Pd) 双金属NP在氧化还原大气中的动态重组和迁移.
- 在催化过程中阐明NP振荡和迁移背后的驱动机制.
主要方法:
- 利用环境传输电子显微镜 (ETEM) 在现场跟踪Cu-Pd NP重组.
- 采用时间解析的微结构分析来观察动态的NP行为.
主要成果:
- 观察到非平衡振荡动力学和持续迁移的像CuxPd/Cu2O纳米结构.
- 确定了Cu-Pd和Cu2O相的空间不对称分布,作为决定NP运动的因素.
- 确定H2/O2反应物的异步扩散是振荡迁移的原因.
- 发现振荡迁移始于Cu原子氧化为Cu2O在低协调的角位点.
结论:
- 了解了催化NP振荡和迁移的机制.
- 提供了对NP迁移诱导的粗化本质的见解.
- 激发了对异质催化中的动态过程的进一步理解.
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