使用水基聚烯树脂从废水中吸附Cr (VI) 离子
Yunwei Huang1,2, Shaoyu Lin1, Pingke Ai3
1School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, China.
Scientific reports
|October 14, 2025
概括
一种新的水基聚烯树脂有效地从废水中去除六价 (Cr(VI)). 这种可持续吸附剂表现出高容量和高效的再生,为净化水提供了有前途的解决方案.
科学领域:
- 环境化学环境化学
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
背景情况:
- 六价 (Cr(VI)) 对环境和健康构成重大风险.
- 有效和可持续的技术对于从污染水中去除Cr6至关重要.
研究的目的:
- 合成和评估一种水性聚烯树脂,用于去除Cr (VI).
- 为了研究吸附机制,动力学和Cr (VI) 去除的热力学.
- 评估树脂的再生效率和可重复使用性.
主要方法:
- 逆乳液聚合利用甲基甲基酸,亚克力酸和无水化.
- 批量吸附实验以确定最佳条件和吸附能力.
- FTIR,SEM和XRD分析用于机制和结构特征.
- 动力,同热和热力学建模.
主要成果:
- 在最佳条件下,合成的树脂实现了98.73%的Cr (VI) 去除.
- 吸附遵循伪二次动力学和兰格穆尔异热模型.
- 据计算,最大吸附能力为142.86 mg/g.
- FTIR证实了通过Cr-O键形成的化学吸收.
- 树脂在5个循环中表现出高的再生效率 (>93%).
结论:
- 水性多烯树脂是一种高效的宏分子吸附剂,用于去除Cr (VI).
- 吸附过程由化学吸附控制,并且在热力学上是有利的.
- 树脂的可重复使用性和高再生效率使其成为污水处理的可持续选择.
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