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生物基双伊他康酸与传统和可再生 (甲基) 烯酸盐的活性比率:减散的影响
Jyoti Gupta1, Radmila Tomovska1,2, Shaghayegh Hamzehlou1
1POLYMAT, Kimika Aplikatua Saila, Kimika Fakultatea, University of the Basque Country UPV-EHU, Joxe Mari Korta Zentroa, Tolosa Hiribidea 72, 20018 Donostia-San Sebastián, Spain.
Biomacromolecules
|October 14, 2025
概括
这项研究探讨了与烯酸盐共聚化可再生双伊塔康酸 (DBI) 的方法. 它成功确定了反应率,显示了生物基聚合物的潜力,减少了成分漂移.
科学领域:
- 聚合物化学 聚合物化学
- 可持续材料科学科学 可持续材料科学
背景情况:
- 对于可持续材料的日益增长的需求推动了人们对可再生单体,如迪布伊他康酸 (DBI) 的兴趣.
- 将DBI与 (甲基) 烯酸盐共聚合起来很困难,原因是传播,消散和反应率低,反应率不利.
研究的目的:
- 研究DBI与常规 (丁烯酸盐,甲基甲烯酸盐) 和生物基 (2-octyl烯酸盐, isobornyl烯酸盐) 单体的溶液共聚合.
- 确定这些共聚合系统的反应率.
- 澄清有关丁烯酸/二丁伊他康酸反应性的文献差异.
主要方法:
- 迪布伊他康酸与丁烯酸盐,甲基甲烯酸盐,二氧烯酸盐和异烯酸盐的溶液共聚合.
- 在现场HNMR光谱学监测共聚合.
- 适合确定反应率的非线性最小平方.
主要成果:
- 对于所有DBI/烯酸盐对来说,都确定了反应率.
- 丁酸/二丁酸伊塔康酸和异酸/二丁酸伊塔康酸系统显示出更有利的共聚合行为.
- 甲基甲基酸盐/二甲基伊塔康酸盐在反应性比率上表现出更大的差异,导致更高的成分漂移.
结论:
- DBI可以与各种烯酸盐共聚合,包括生物基选项.
- 与丁烯酸乙烯酸,2-烯酸乙烯酸和异烯酸乙烯酸联合聚合,与甲基甲烯酸相比,可以更好地控制聚合物组成.
- 这项研究为开发使用DBI的高性能生物基聚合物提供了关键数据.
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