矿衍生硬碳的内源模板导向拓工程,用于动力加速储存
Shiyue Li1, Hongting Yin1, Zhiwei Xing1
1School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing, 100083, P. R. China.
Angewandte Chemie (International ed. in English)
|October 14, 2025
概括
研究人员开发了一种使用煤炭制造离子电池 (SIB) 硬碳阳极的新方法. 这种方法增强了闭孔结构,大大提高了储存能力和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 煤炭是离子电池 (SIB) 中硬碳阳极的可行前体.
- 煤炭衍生碳中的石墨化和π-π相互作用限制了层间间距和性能.
- 优化硬碳结构对于先进的SIB来说至关重要.
研究的目的:
- 开发一个基于煤炭的硬碳的自我模板策略.
- 在分子层面设计闭孔结构,以增强储存.
- 调查功能组在改善硬碳特性中的作用.
主要方法:
- 在煤炭碳化过程中使用了自我模板策略.
- 引入基 (-OH) 和碳基 (CO) 基来控制孔隙结构和石墨化.
- 研究了用于混合有机-无机固体电解质介相 (SEI) 形成的表面功能改造.
- 在离子电池中测试了基于煤炭的硬碳作为阳极.
主要成果:
- 在50 mA g-1下达到350 mAh g-1的高可逆容量.
- 经过8000次5Ag-1循环后,证明了出色的循环稳定性,保持了88%的容量.
- 证实了闭孔结构和混合有机-无机SEI的形成.
- 带有NVP阴极的充满电池显示稳定的循环性能.
结论:
- 自建模策略有效调节基于煤炭的硬碳中的闭孔结构.
- 碳基在防止石墨化和增强储存方面发挥着关键作用.
- 这种方法为SIBs开发高性能硬碳阳极提供了一个有前途的途径.
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