通过对环氧树脂的硬化改性来开发环氧树脂-竹复合材料
Yanchao Liu1, Yuan Niu2, Dingyuan Zheng2
1College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin, 150001, China.
International journal of biological macromolecules
|October 14, 2025
概括
热塑性聚氨 (TPU) 显著增强了竹复合材料,比聚硫 (PES) 更有效地提高了机械性能和性. 这一发展为建筑应用中塑料提供了一个可持续的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 复合材料 复合材料 复合材料
背景情况:
- 环氧树脂-竹复合材料提供高强度和低收缩,与线对齐.
- 用竹子取代塑料,使用竹子
- 倡议 (initiative) 是指一个主动的行为.
- 然而,固有的脆性和不良的抗候性限制了它们的应用.
- 固环氧树脂对于提高竹复合材料性能至关重要.
研究的目的:
- 研究热塑性聚氨 (TPU) 和聚硫 (PES) 作为环氧树脂-竹复合材料的硬化剂的有效性.
- 为了比较TPU修饰和PES修饰的竹环氧复合材料的机械性能和硬化机制.
主要方法:
- 使用TPU和PES制备了两个硬化环氧系统.
- 竹环氧复合材料 (EP-TPU/BF和EP-PES/BF) 是使用这些改性树脂制造的.
- 机械性能 (柔性强度,抗拉强度,弹性模量,性) 被比较评估.
主要成果:
- 无论是TPU还是PES,都提高了复合材料的性能,TPU显示出明显更大的增强.
- EP-TPU/BF复合材料的屈曲强度增加了101.3% (286.2 MPa),拉伸强度增加了30.7% (258.93 MPa),弹性模量增加了76% (9.7 GPa),性增加了104% (37.91 MJ/m3).
- TPU的硬化机制包括增强的界面粘附,减少相位分离和有效的能量吸收.
结论:
- 热塑性聚氨 (TPU) 是一种比聚硫 (PES) 更有效的固剂,用于竹环氧复合材料.
- EP-TPU/BF复合材料的增强机械性能扩大了它们在建筑中的潜在应用.
- 这项研究为开发高性能,环保的竹基材料提供了可行的策略.
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