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Updated: Jan 15, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
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Published on: May 28, 2014

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选择性氨 (III) /欧 (III) 分离通过C-N合南罗林衍生的比斯 (pyrazole) 连接物

Tengfei Cui1, Qing Chang1, Qiao Chen1

  • 1Radiochemistry Laboratory, School of Nuclear Science and Technology, Lanzhou University, 730000 Lanzhou, China.

Inorganic chemistry
|October 14, 2025
PubMed
概括

新的N-捐赠体连接物有效地将三价性活性化物 (An(III)) 从核废物管理中至关重要的兰坦化物 (Ln(III) 进行分离. 这些配体在酸性介质中表现出高的选择性和提取效率,推进了燃料循环策略.

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
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