聚合物捐赠者的模块化设计调节有机太阳能电池的溶液聚合和伸展性
Xuanang Luo1, Xinrui Liu1, Youran Lin1
1Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, South China University of Technology, Guangzhou, 510640, China.
Angewandte Chemie (International ed. in English)
|October 15, 2025
概括
研究人员开发了一种新的聚合物,用于使用非化溶剂的环保有机太阳能电池 (OSC). 这种设计改善了薄膜结构,将效率提高到19.9%,并使高度可拉伸的太阳能电池成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 聚合物化学 聚合物化学
背景情况:
- 由于环境问题,有机太阳能电池 (OSC) 制造需要非化溶剂.
- 在OSC中实现最佳的薄膜形态和高设备性能是这些溶剂的挑战.
- 控制溶液状态聚合到纤维状网络是高性能OSC的关键.
研究的目的:
- 开发一种模块化分子设计策略,用于用于非化溶剂加工OSC的聚合物.
- 为了实现同时调节能量水平,晶体包装和链条灵活性.
- 创建高效率,机械坚固,环境可持续的OSCs.
主要方法:
- 使用PTzBI聚合物平台采用模块化分子设计策略.
- 一种新型的聚合物,PTzBI-dF-Si,用化骨干和西洛终结侧链合成.
- 分析了溶液聚合,薄膜形态,设备性能和机械性能.
主要成果:
- PTzBI-dF-Si在o-xylene中显示出平衡的溶解性和受控的溶液状态聚合.
- 聚合物形成了类似网络的聚合物,导致固体薄膜中的结晶性和纤维状形态增强.
- 在刚性OSC中,PTzBI-dF-Si:L8-BO混合物实现了19.9%的功率转换效率 (PCE).
- 本质上可拉伸的OSC实现了超过16%的PCE,由于延展性变形 (∼20%的骨折应变),在40%的应变下保持了>80%.
结论:
- 合理的模块化聚合物设计有效地促进了非化溶剂加工的OSC.
- 开发的PTzBI-dF-Si聚合物提供了高效率和机械强度.
- 这种方法对可扩展和可穿戴电子应用具有前景.
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