通过自动化SEM-EDX颗粒分析方法在受控条件下释放的防涂层中的微塑料的表征
Matthias Bork1, Søren Kiil1, Petre-Flaviu Gostin1
1CoaST, Department of Chemical and Biochemical Engineering, Technical University of Denmark, DTU, Building 229, Kongens Lyngby, 2800, Denmark.
Environmental pollution (Barking, Essex : 1987)
|October 15, 2025
概括
海洋防涂料在航行期间释放微塑料. 这项研究量化了在模拟航行下从游艇涂层中释放的粒子,揭示了释放率和粒子组成.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 海洋生物学 海洋生物学
背景情况:
- 微塑料对海洋生态系统构成重大威胁.
- 船舶船体上的防涂层是海洋微塑料的主要来源.
- 了解这些涂层中的微塑料释放机制对于缓解至关重要.
研究的目的:
- 在模拟航行过程中,从防涂层释放的微塑料颗粒量化.
- 描述释放的粒子的大小,数量和化学成分.
- 为了将颗粒的释放与防涂料的自我抛光行为相关联.
主要方法:
- 模拟的低速航行条件被用于在人造海水中暴露商业防游艇涂层.
- 采用了包括扫描电子显微镜和能量分散式X射线光谱 (SEM-EDX) 在内的自动化粒子分析.
- 随着时间的推移,对人工海水中的颗粒含量,大小和化学成分进行监测.
主要成果:
- 从防腐涂层中观察到微塑料颗粒的释放,并且在暴露期间增加.
- 大多数释放的粒子的直径相当于1-5μm.
- 颗粒主要由碳组成 (58%重量). ),氧气 (32%的重量). ),铜 (0-8%的重量). ) 和 (0-2%重量). ) 来自涂层的粘合剂和生物杀菌剂.
结论:
- 这项研究表明,在航行过程中,微塑料从防涂层中释放的直接途径.
- 颗粒物释放率与涂料的抛光特性有关.
- 这些发现有助于更好地了解来自海上活动的微塑料污染.
相关概念视频
Scanning Electron Microscopy
A scanning electron microscope (SEM) is used to study the surface features of a sample by using an electron beam that scans the sample surface in a two-dimensional manner. Typically, areas between ~1 centimeter to 5 micrometers in width can be imaged. SEM can be used to image bacteria, viruses, tissues as well as larger samples like insects. Conventional SEM gives a magnification ranging from 20X to 30,000X and spatial resolution of 50 to 100 nanometers.
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To be visualized by an electron microscope, either transmission or scanning, biological samples need to be fixed (stabilized) so the electron beam does not destroy them and dried thoroughly (desiccated/dehydrated) so the vacuum does not affect them. Fixation needs to be done as quickly as possible because the sample properties will start changing as soon as it is removed from its natural environment. For example, in a tissue sample, the oxygen levels begin decreasing, causing an altered...


